Development of (quinolinyl)amido-based pincer palladium complexes: A robust and phosphine-free catalyst system for C-H arylation of benzothiazoles -
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|Development of (quinolinyl)amido-bas ...
(Quinolinyl)amido-ligated palladium(II) complexes have been synthesized and applied in the catalytic C-H bond arylation of benzothiazoles. The tridentate ligand precursors, R2N-C(O)CH2-(NH)-C9H6N [(R2NNN8-Q)-H; R2N = morpholinyl, Me-N-piperazinyl] and the pincer palladium complexes, [κN,κN,κN-{R2N-C(O)CH2-(μ
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|Pressure-Stabilized Superconductive ...
High-pressure structures of tantalum hydrides were investigated over a wide pressure range of 0–300 GPa by utilizing evolutionary structure searches. TaH and TaH2 were found to be thermodynamically stable over this entire pressure range, whereas TaH3, TaH4, and TaH6 become thermodynamically stable at pressures greater than 50 GPa. The dense Pnma (TaH2), R3?m (TaH4), and Fdd2 (TaH6) compounds possess metallic character with a strong ionic feature. For the highly hydrogen-rich phase of Fdd2 (TaH6), a calculation of electron–phonon coupling reveals the potential high-Tc superconductivity with an estimated value of 124.2–135.8 K.
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太仓市汽车流通行业商会为经销商搭台
【摘要】：正由太仓汽车流通商会主办的2010年太仓新春大型汽车展销会于3月27-28日在南洋广场举办。太仓市工商联主席、总商会会长宋福荣、太仓市商务局副局长杨剑等市有关部门的
【关键词】：
【分类号】：F426.471【正文快照】：
由太仓汽车流通商会主办的2010年太仓新春大型汽车展销会于3月27-28日在南洋广场举办。太仓市工商联主席、总商会会长宋福荣、太仓市商务局副局长杨剑等市有关部门的领导应邀出席开幕仪式。汽车展销会期间,适逢双周休闲日,天气宜人。整个太仓城厢镇游人非常多,尤其是南洋广场
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